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UV AOP chamber BS-OX: photochemical surface cleaning with 185 nm and ozone

The BS-OX is a UV AOP irradiation chamber for photochemical surface cleaning, ozone treatment and targeted contact angle modification. It removes organic contamination and raises the surface energy before parts are bonded, coated or printed – without wet-chemical pretreatment. In an oxygen-reduced atmosphere with typically 1 % oxygen, 185 nm generates ozone and reactive oxygen species that oxidise residues; 254 nm covers disinfection and direct photolysis. Eight UVC lamps can be fitted ozone-free, ozone-generating or mixed (4+4).

Photochemical cleaning and activation with 185 nm UVC in an oxygen-reduced atmosphere leads to ozone formation and the generation of reactive oxygen species. These efficiently oxidize organic contaminants and increase surface energy. This results in improved wettability and a reproducible reduction in the contact angle. This interplay of 185 nm UVC, ozone and radicals is an advanced oxidation process (AOP) – hence the name UV AOP chamber.

At the same time, the UV radiation is energetic enough to split organic compounds, for example.

The 185 nm spectrum is used for ozone and radical formation as well as direct photolysis of organic residues.

The underlying mechanism is described in Surface cleaning and activation with UVC.

The 254 nm wavelength also enables classic UVC processes such as disinfection and pretreatment for coating processes.

The BS-OX can operate with 8 ozone-free or ozone-generating UVC lamps. A mixed configuration in a 4+4 ratio allows for optional operation with an ozone-containing or ozone-free process atmosphere, thus supporting precise control of cleaning, oxidation, and surface activation.

All internal surfaces are made of uncoated metals and quartz glass. Organic coatings or polymer-based protective layers are completely dispensed with. This means that there are no degradation products and no outgassing under 185 nm/254 nm irradiation. The result is a process chamber with stable boundary conditions for surface cleaning, ozone treatment, and reproducible contact angle changes.

The BS-OX is designed for industrial and scientific applications in which organic residual films, photoresist residues, or adsorbates limit the functionality of components.

Fields of application for AOP chamber BS-OX

  • Activation of polymer, glass, ceramic, and metal surfaces prior to bonding, sealing, or coating
  • Cleaning of optical components, wafers, microchips, and filters with subsequent increase in the polar surface area
  • Adjustment of contact angle and surface energy for microfluidics, medical technology, and sensor technology
  • Sterilization and degradation of odor- or color-active organic contaminants

Dual irradiation at 185 nm and 254 nm enables reliable degradation of organic residues through photolysis and downstream ozone/oxidation & radical reactions.
At the same time, the polar portion of the surface increases, which defines the wettability and contact angle.

Based on the proven BS irradiation chamber platform, a homogeneous, high-performance UVC sample chamber with generous internal dimensions is available. Short process times, moderate sample temperatures, and flexible lamp configurations qualify the BS-OX as a robust system for research, development, and production, especially in semiconductor and optics manufacturing as well as in the surface pretreatment of modern materials.
 

 

Technical data of AOP chamber BS-OX

Interior chamber 50 x 30 x 25 cm
Dimensions, chamber 81 x 59 x 63 cm
Dimensions, UV-MAT 19 x 25 x 10 cm
Weight ~ 60 kg
Irradiation time 0,01 s to 9999 h
Power consumption 225 W
Mains 230 VAC, 2 A
Operation temperature 10 to 40 °C
Humidity < 80% non-condensing
Lamp lifetime up to 8.000 h
Number of lamps 8
Lamp type UVC, ozone generating
  alternative: ozone free
Lamp power 20 W each
Sample temperature 45 °C +/- 5°C
Gas inlet / Gas outlet Festo QSK-G1/4-10 for
  10 mm hose diameter
Exhaust air DN 100 connetor for
  Corrugated metal hose and
  suitable exhaust air treatment
Classification Group 0 acccording to
  DIN EN 12198:2000

Frequently asked questions about ozone and exhaust air on the BS-OX

Can the chamber be opened immediately after the ozone process?
No. While irradiation is running, the door of the BS-OX is locked. Once irradiation has ended the door is not released straight away: the integrated purge control first carries out the specified purge and extraction phase and only then unlocks the door. This rules out the chamber being opened directly after the ozone process, with the operator exposed to the ozone still present.

How long does the purge phase after the ozone process take?
Allow for 5 minutes. The ozone concentration that actually remains depends on mixing, load and initial concentration and is to be assessed as part of the operator's risk assessment.

Is the amount of ozone in the process measured with the door closed?
Continuous measurement of the ozone concentration inside the closed chamber is not part of the standard BS-OX. The concentration actually present depends on several process parameters: the lamp configuration (ozone-generating, ozone-free or mixed 4+4), the irradiation time, the oxygen concentration, the air flow and the oxidation reactions taking place inside the chamber. In addition, oxygen and ozone sensors age comparatively quickly and have to be calibrated about every six months – a permanently installed measurement therefore creates continuous maintenance effort. In practice, reproducible results are achieved by keeping the process parameters constant.

How strong does the exhaust air have to be, and is there a minimum and maximum air volume?
The BS-OX has a DN 100 connection and is intended for connection to suitable exhaust air or exhaust air treatment. A generally valid minimum or maximum volume flow in l/min cannot sensibly be specified, because it depends on the particular installation and on the intended process. As a guide value for extraction, assume one chamber volume per minute, that is about 40 l/min or 2.4 m³/h. What matters is the direction of the effect: a high continuous air exchange during irradiation reduces the ozone concentration inside the chamber and thus weakens the process, whereas a high volume flow is desirable during the purge phase.